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This protocol employs tert-butyl hydroperoxide as the sole reagent of the reaction to combine coumarins and ethers in reasonable yields under metal- and solvent-free reaction conditions. Vanessa mata boa sorte torrents page 1 of 82.Ī regioselective direct alkylation of coumarins at C-3 via cross-dehydrogenative coupling of unactivated Csp 2–Csp 3 bonds is developed.
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